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Ceramics are brittle due in large part to the limited availability of energy dissipation pathways when they are subjected to an impact load. The primary avenue for improving the material reliability and energy-absorption capability is to create new energy dissipation mechanisms that can be used to replace or minimize the kinetic energy associated with the debris shattering. In this paper, a computational framework is developed to investigate the relationship between phase composition and energy dissipation pathways in polymer derived ceramic (PDC) composites by accounting for the key processing parameters and deformation/failure mechanisms. It is found that the phase composition that promotes both the Mullins effect and the ligament bridging mechanism can significantly improve the structural integrity of the composite material. A fundamental understanding of how to redistribute the impact energy dissipation in a controllable path would hold great promise for fabricating PDC composites with tailored properties. 

Meteorites preserve evidence of processes on their parent bodies, including alteration, metamorphism, and shock events. Here we show that the Kakowa (L6) ordinary chondrite (OC) preserves both shock-melt veins and pockets of detrital grains from a brecciated and altered object, including corundum, albite, silica, fayalite, forsterite, and margarite in a Pb- and Fe-rich matrix. Preservation of the observed mineralogy and texture requires a sequence of at least two impacts: first, a high-velocity collision formed the shock melt veins containing the high-pressure minerals ringwoodite, wadsleyite, majorite, and albitic jadeite; later, a low-velocity impact formed fractures and filled them with the detrital material. Oxygen and Pb isotope ratios suggest an OC origin for these detrital minerals. Although fluid alteration is common in carbonaceous chondrites, the discovery of margarite with an OC oxygen isotopic signature is novel. Kakowa extends both the impact and alteration history of L6 ordinary chondrites in general.

 

Polymer-derived ceramics (PDCs) which are fabricated through pyrolysis of preceramic polymers have attracted increasing attention due to their versatility in structure architecture design and property tailoring. Shaping at the polymer state using 3D printing allows the final ceramic products to exhibit arbitrary shapes and complex architectures that are otherwise impossible to achieve through traditional processing routes. The polymer-to-ceramic phase transition also provides additional space for mechanical property tailoring. A multiscale computational model is developed to explore the phase transition mechanisms and their correlations with processing parameters and mechanical response. Calculations in this work concern PMHS/DVB. Molecular dynamics simulations are carried out first to track the chemical reaction mechanisms and atomic structure evolution. The density of generated gas during pyrolysis is transferred to the finite element model (FEM) for coupled heat transfer and phase transition analysis. FEM calculations reveal the effect of pyrolysis temperature and heating rate on structure-level phase composition and elastic modulus. It is found that there is a threshold of pyrolysis temperature above which full ceramic phase is formed. Higher heating rate promotes ceramization and leads to higher elastic modulus. In addition, volume shrinkage is found to accelerate ceramic formation which slightly enhances material strength. 

Abstract The search for a dark photon holds considerable interest in the physics community. Such a force carrier would begin to illuminate the dark sector. Many experiments have searched for such a particle, but so far it has proven elusive. In recent years the concept of a low mass dark photon has gained popularity in the physics community. Of particular recent interest is the 8 Be and 4 He anomaly, which could be explained by a new fifth force carrier with a mass of 17 MeV/ c 2 . The proposed Darklight experiment would search for this potential low mass force carrier at ARIEL in the 10-20 MeV/ c 2 e + e − invariant mass range. This proceeding will focus on the experimental design and physics case of the Darklight experiment.